Asymmetric catalytic oxidation
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Asymmetric catalytic oxidation is a technique of oxidizing various substrates to give an enantiopure product using a catalyst.[1][2]
Reactions
- Jacobsen epoxidation of alkenes using manganese-salen complex and NaOCl
- Sharpless epoxidation of allyl alcohols using titanium isopropoxide, diethyl tartrate, and tert-butyl hydroxyperoxide[3]
- Sharpless asymmetric dihydroxylation of alkenes using dihydroquinine or dihydroquinidine ligands on an osmium metal center
- Sharpless oxyamination
- Shi epoxidation of alkenes using oxone and a fructose-derived chiral catalyst
- Sulfonyloxaziridine enolate oxidation
References
- ^ Wang, Yizhan; Li, Haolong; Qi, Wei; Yang, Yang; Yan, Yi; Li, Bao; Wu, Lixin (2012-04-10). "Supramolecular assembly of chiral polyoxometalate complexes for asymmetric catalytic oxidation of thioethers". Journal of Materials Chemistry. 22 (18): 9181–9188. doi:10.1039/C2JM16398E. ISSN 1364-5501.
- ^ Muñiz, Kilian; Nieger, Martin (2003-10-01). "Ferrocenoyl-Substituted Cinchona Alkaloids: Synthesis, Structure, and Application in Asymmetric Catalytic Oxidation". Organometallics. 22 (22): 4616–4619. doi:10.1021/om0304457. ISSN 0276-7333.
- ^ Dai, Wen; Li, Jun; Chen, Bo; Li, Guosong; Lv, Ying; Wang, Lianyue; Gao, Shuang (2013-11-15). "Asymmetric Oxidation Catalysis by a Porphyrin-Inspired Manganese Complex: Highly Enantioselective Sulfoxidation with a Wide Substrate Scope". Organic Letters. 15 (22): 5658–5661. doi:10.1021/ol402612x. ISSN 1523-7060.
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