Potassium sulfite

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Potassium sulfite
Potassium sulfite.png
Names
IUPAC name
Potassium sulfite
Other names
E225
Identifiers
3D model (JSmol)
ChemSpider
UNII
  • InChI=1S/2K.H2O3S/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2 ☒N
    Key: BHZRJJOHZFYXTO-UHFFFAOYSA-L ☒N
  • InChI=1/2K.H2O3S/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2
    Key: BHZRJJOHZFYXTO-NUQVWONBAU
  • [O-]S(=O)[O-].[K+].[K+]
Properties
K2SO3
Molar mass 158.26 g/mol
Appearance White solid
Soluble
Acidity (pKa) 8
−64.0·10−6 cm3/mol
Hazards
Flash point Non-flammable
Related compounds
Other anions
Potassium sulfate
Potassium selenite
Other cations
Sodium sulfite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Potassium sulfite is the inorganic compound with the formula K2SO3. It is the salt of potassium cation and sulfite anion. It is a white solid that is highly soluble in water.

Use

Potassium sulfite is widely used for preserving food and beverages.

Production and reactions

Potassium sulfite is produced by the thermal decomposition of potassium metabisulfite at 190°C:[1]

K2S2O5 → K2SO3 + SO2

References

  1. ^ Johnstone, H. F. (1946). "Sulfites and Pyrosulfites of the Alkali Metals". Inorganic Syntheses. 2: 162–167. doi:10.1002/9780470132333.ch49. ISBN 9780470132333.